The Mechanistic and Oxidative Study of Methomyl and Parathion Degradation by Fenton Process

نویسندگان

  • Chihhao Fan
  • Ming - Chu Liao
چکیده

The purpose of this study is to investigate the chemical degradation of the organophosphorus pesticide of parathion and carbamate insecticide of methomyl in the aqueous phase through Fenton process. With the employment of batch Fenton process, the degradation of the two selected pesticides at different pH, initial concentration, humic acid concentration, and Fenton reagent dosages was explored. The Fenton process was found effective to degrade parathion and methomyl. The optimal dosage of Fenton reagents (i.e., molar concentration ratio of H2O2 to Fe) at pH 7 for parathion degradation was equal to 3, which resulted in 50% removal of parathion. Similarly, the optimal dosage for methomyl degradation was 1, resulting in 80% removal of methomyl. This study also found that the presence of humic substances has enhanced pesticide degradation by Fenton process significantly. The mass spectroscopy results showed that the hydroxyl free radical may attack the single bonds with least energy of investigated pesticides to form smaller molecules which is more easily to degrade either through physio-chemical or bilolgical processes. Keywords—Fenton Process, humic acid, methomyl, parathion, pesticides

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Use of Fenton Reagent as Advanced Oxidative Process for Removal of Basic and Acid Red Dyes from Aqueous Solutions

In this study, the Fenton process was used to investigate the color removal efficiency of Acid Red 52 and Basic Red 18 dye solutions by direct chemical oxidation. Color and chemical oxygen demand (COD) was successfully removed more than 99% and up to 92% respectively. This article would provide an easy assessment of the viability of using Fenton reagent in acidic conditions, so it is a prom...

متن کامل

Decolorization and Degradation of Basic Blue 3 and Disperse Blue 56 Dyes Using Fenton Process

In this study, oxidative discoloration of Basic blue3 (B.B3) and Disperse blue56 (D.B56) dyes in synthetic textile wastewater has been studied using Fenton (Fe2+/H2 O2 ) process. The Fenton’s technique showed satisfactory color removal efficiency. The operating parameters such as concentration of Fe2+, dose of H2 O2 , initial concentration of dye, time contact, initial volume of wastewater that...

متن کامل

Application of Electro-Fenton (EF) Process to the Removal of Pentachlorophenol from Aqueous Solutions

Pentachlorophenol (PCP) is a very hazardous compound which enters into the environment by industries such as refineries and petrochemicals. As its biological degradation is very slow, this use may cause the pollution of soils and groundwater; with the recent emergence of pentachlorophenol contamination as an important drinking water quality issue, finding an easy, economical, and useful method ...

متن کامل

Evaluating the Efficiency of the Fenton-Ultrasonic Process in Degradation of Trihalomethanes Precursors from Aqueous Environments Using Zero Iron by Response Surface Method

Background: The reaction of natural organic matters (NOMs) with chlorine in the conventional disinfection process results in disinfection by-products (DBP) such as trihalomethanes and haloacetic acids. Due to the potential health risks of trihalomethanes for public health, it has attracted a lot of attention. The purpose of this study is to investigate the performance of combined Fenton-ultraso...

متن کامل

Optimized Removal of Sodium Dodecylbenzenesulfonate by Fenton-Like Oxidation Using Response Surface Methodology

This study investigates the degradation of sodium dodecylbenzenesulfonate (SDBS) in aqueous solution by the Fenton-like oxidation process. The effects of different parameters such as concentrations of ferric chloride and hydrogen peroxide, pH and reaction time on the SDBS removal and Chemical Oxygen Demand (COD) reduction were evaluated. Response Surface Methodology (RSM) with Central Compo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2009